The two teams traded blows throughout a thrilling 90 minutes, but City claimed a 4-2 victory to book their place in the knockout stage.
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Sergio Aguero became Manchester City's all-time record goal scorer after scoring against Serie A giants, Napoli in a Champions League encounter on Wednesday night. He has scored 107 in 154 Premier League matches at a rate of a goal every 106 minutes.
As in the initial meeting in Manchester, events unfolded at a brisk pace from the opening whistle but it was City - smothered by the Napoli press - who found themselves on the back foot on this occasion.
Eight minutes later Mertens turned provider when he played a precise pass to Lorenzo Insigne who turned the ball home in clinical fashion from 12-yards out, 1-0.
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City crafted their first clear opening after the half hour when Aguero's clever lay-off to Kevin De Bruyne launched a break that ended with the Argentina striker's low effort deflecting narrowly wide. The Argentine then surged into the Napoli penalty box, and proceeded to power the ball home into the bottom right-hand corner, as he became City's all-time goalscorer with a whopping 178 goals to his name.
City celebrate scoring against Napoli.
Five minutes into the second half Stones did find the back of the net for City when he met a corner-kick with a powerful header that beat the Napoli keeper, 2-1.
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